New open-framework BERYLLIUM PHOSPHATE (cas 13598-15-7)s with hcb, sql, and bnn topologies
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Add time:08/26/2019 Source:sciencedirect.com
Three new beryllium phosphates, namely, H3aep·Be2(PO4)2(H2PO4)·H2O (1), H2tmdp·Be3(HPO4)3(PO4CH3)·2.25H2O (2), and H2dmpda·Be3(PO4)(HPO4)2(H2PO4) (3), were prepared under solvothermal conditions. These compounds display different open-framework structures with hcb (for 1), sql (for 2), and bnn (for 3) topologies, respectively. The formation of phosphate ester from in situ esterification reaction of phosphoric acid and methanol is noteworthy.
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