All-solid-state cells with Li4Ti5O12/carbon nanotube composite electrodes prepared by infiltration with argyrodite sulfide-based solid electrolytes via liquid-phase processing

Add time:09/02/2019    Source:sciencedirect.com

All-solid-state cells are safe, and have high energy densities and power densities. Sulfide-based solid electrolytes (SEs) exhibit high ionic conductivities and favorable mechanical properties allowing for the facile preparation of all-solid-state cells via simple mixing and cold-pressing processes. For practical applications, it is necessary to produce SEs and all-solid-state cells more efficiently. Herein, a novel fabrication process for homogeneous composite electrodes used in all-solid-state cells was successfully demonstrated using an infiltration technique. The Li4Ti5O12 and carbon nanotube ([email protected]) porous electrode was infiltrated with a precursor solution containing an argyrodite Li6PS5Br SE, and the solvent was removed by drying at 150 °C under vacuum to prepare an infiltrated [email protected] electrode. The process without conventional mixing formed an electrochemically active interface with a large contact area and favorable conduction pathways. The all-solid-state cell with the [email protected] electrode showed an improved capacity of 163 mAh g−1 compared to those prepared with the dry-mixed electrodes at 25 °C, and the high capacity was maintained for 500 cycles. Moreover, the cell with the [email protected] electrode showed a reversible capacity of 100 mAh g−1 or more at 4 C-rate and 100 °C. Thus, the infiltration process is effective for the practical fabrication and application of all-solid-state cells.

We also recommend Trading Suppliers and Manufacturers of beryllium sulphide (cas 13598-22-6). Pls Click Website Link as below: cas 13598-22-6 suppliers

Prev:Friction behaviour evaluation in beryllium–copper threaded connections
Next:Electrochemical study of Pd capped SAMARIUM HYDRIDE (cas 13598-32-8) thin film switchable mirror)