Samarium-mediated intramolecular cross-couplings of an α,β-unsaturated N-acylpyrrole
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Add time:08/30/2019 Source:sciencedirect.com
The first example of an α,β-unsaturated N-acylpyrrole undergoing a SmI2-mediated cyclization is reported. In contrast to other unsaturated units, the intermediate samarium enolate readily engages in aldol-type reactions, necessitating careful control of the reaction conditions.
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