Phosphorous acid (cas 13598-36-2) promoted isomerization of propargyl alcohols to α,β-unsaturated carbonyl compounds
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Add time:08/26/2019 Source:sciencedirect.com
A metal-free and two-phase protocol for the Meyer-Schuster isomerization of propargyl alcohols to the corresponding α,β-unsaturated carbonyl compounds has been achieved in the presence of stoichiometric Phosphorous acid (cas 13598-36-2) aqueous solution, which produces the desired products in high yields with excellent stereoselectivity. Compared with the traditional methods, the procedure features broad scope of the substrates, mild conditions, and easy separation, providing an appealing alternative to the Meyer-Schuster reaction.
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