Synthesis and structure of a novel tetranuclear 32-membered macrocycle of triphenyltin complex with Pyridine-4-carboxylic acid N-oxide (cas 13602-12-5)
-
Add time:08/26/2019 Source:sciencedirect.com
The 32-membered stereoregular triphenyltin macrocycle: [Ph3Sn (OCOC5H4NO)]4·3(CH2Cl2) has been synthesized by the reaction of triphenyltin chloride with pyridine-4-carboxylic acid N-oxide. The complex was characterized by elemental analysis, FT-IR, NMR (1H, 119Sn) spectra and X-ray crystallography. Single crystal X-ray diffraction data reveal that the complex is highly symmetrical tetranuclear cyclic complex with the ligand pyridine-4-carboxylic acid N-oxide bridging the adjacent tin atoms. All four tin atoms are five-coordinated resulting in trigonal bipyramidal geometry. And the complex showed good thermal stability and high antitumor activity.
We also recommend Trading Suppliers and Manufacturers of Pyridine-4-carboxylic acid N-oxide (cas 13602-12-5). Pls Click Website Link as below: cas 13602-12-5 suppliers
Prev:Syntheses, crystal structures and DNA binding potential of copper(II) carboxylates
Next:Structural development of 1H-pyrazolo-[3,4-b]pyridine-4-carboxylic acid derivatives as human peroxisome proliferator-activated receptor alpha (PPARα)-selective agonists) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Synthesis, spectral and X-ray diffraction of two new 2D lead(II) coordination polymers formed by nicotinic acid N-oxide linkers09/03/2019
- Synthesis and characterization of pyridine N-oxide complexes of manganese, copper and zinc09/02/2019
- Assembly of diverse structural types of organotellurium compounds in the reactions of (4-MeO-C6H4)2TeO with pyridine carboxylic acids09/01/2019
- Electrochemical performance of hydrothermally synthesized N-Doped reduced graphene oxide electrodes for supercapacitor application08/31/2019
- Complexation of thorium with pyridine monocarboxylate-N-oxides: Thermodynamic and computational studies08/30/2019
- A novel 1D molybdenum oxide ribbon bridged by pyridine-4-carboxylic ligands: [(C6H4NO2) Mo2O5OH]08/29/2019
- The sequence of deprotonation of pyridine-6-phospho-4-carboxylic acid08/28/2019
- Structural development of 1H-pyrazolo-[3,4-b]pyridine-4-carboxylic acid derivatives as human peroxisome proliferator-activated receptor alpha (PPARα)-selective agonists08/27/2019
-
Health and Chemical more >