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  • Perspective ArticlePalladium nanoparticles dispersed on the hollow aluminosilicate [email protected] γ-AlOOH as an excellent catalyst for the hydrogenation of nitroarenes under ambient conditions

  • Add time:09/01/2019    Source:sciencedirect.com

    In this study, a novel catalyst has been prepared through supporting Pd nanoparticles (NPs) on the surface of boehmite (γ-AlOOH) based hollow aluminosilicate microspheres ([email protected]γ-AlOOH). The prepared Pd/[email protected]γ-AlOOH catalyst has high catalytic activity for the hydrogenation of nitroarenes to their corresponding amino derivatives with high yields at ambient conditions. The high catalytic efficiency is attributed to the large pore size of the flower-like hierarchical flakes structure of [email protected]γ-AlOOH, that gives Pd NPs on the support surface easy accessibility. Moreover, the Pd/[email protected]γ-AlOOH catalyst can also be easily recycled at least five times without obvious decrease of catalytic activity. This work may provide a useful method for the fabrication of supported noble metal NP-based catalysts on the surface of mesoporous hierarchical structure materials with easy accessibility and superior activity.

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