Asymmetric synthesis of aryl cyclitols based on 1,2,3,4-Tetrahydronaphthalene (cas 119-64-2) scaffolds
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Add time:09/03/2019 Source:sciencedirect.com
A series of aryl cyclitols based on a 1,2,3,4-Tetrahydronaphthalene (cas 119-64-2) scaffold have been synthesized in a stereocontrolled manner. These cyclitols possess four contiguous stereocenters amongst which one is a quaternary stereocenter, which has been constructed by applying enzymatic kinetic resolution reaction. The remaining stereocenters have been created by substrate directed asymmetric dihydroxylation reaction and stereoselective keto-reduction process.
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