The new Ru(NBD)Cl2(substituted-2,2′-biquinoline) complexes. Synthesis and characterization
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Add time:09/02/2019 Source:sciencedirect.com
A new ruthenium complex series of type Ru(NBD)Cl2L (with L = 2,2′-biquinoline derivative) was prepared. Their spectroscopic properties were analysed by RMN 1H, UV–Vis and Infrared and their electrochemical potentials were obtained by cyclic voltammetry technique. The structure for a complex of this series was established by X-ray analysis. This structure shows a planarity distortion of biquinoline ligand on the complex. The coplanarity distortion degree through the complex series is modulated by the 3,3′-substitued position on the 2,2′-biquinoline ligand, and show correlation with the differences observed on their spectroscopic properties.
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