The methylation of arsenate by a marine alga Polyphysa Peniculus in the presence of L-METHIONINE-METHYL-D3 (cas 13010-53-2)

Add time:08/28/2019    Source:sciencedirect.com

Polyphysa peniculus growing in artificial seawater methylates arsenate to produce a dimethylarsenic derivative, probably dimethylarsinate. When L-methionine-methyl-d3 is added to the culture the CD3 label is incorporated intact in the dimethylarsenic compound to a considerable extent, indicating that S-adenosylmethionine, or some related sulphonium compound, is involved in the biological methylation. Conclusive evidence of the CD3 incorporation was provided by using a specially developed hydride generation-gas chromatography-mass spectrometry methodology.

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