Short communicationA new chemical synthesis of 5α-cholest-8(14)-en-3β,5α-diol
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Add time:08/28/2019 Source:sciencedirect.com
Reduction of 3β-benzoyloxy-14α,15α-epoxy-5α-cholest-7-ene with lithium in ethylenediamine gave 5α-cholest-8(14)-en-3β, 5α-diol in high yield. This procedure offers an alternate synthesis through the reductive rearrangement of an α,β-unsaturated steroidal epoxide.
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