Racemic syntheses of agelasimine-A and agelasimine-B, bicyclic diterpenoids from the marine sponge Agelas mauritiana

Add time:08/29/2019    Source:sciencedirect.com

The first racemic syntheses of agelasimines-A and -B, adenine-related bicyclic diterpenoids from the marine sponge Agelas mauritiana, have been accomplished by means of routes through the diol 10 as a key intermediate for their common diterpene portion. As a result, their structures and relative stereochemistries have been unequivocally established to be those represented by formulas (±)-1a and (±)-2a, respectively.

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