Difluoroallylation using a 2-bromomethyl-1,1-difluoroalk-1-ene

Add time:08/28/2019    Source:sciencedirect.com

Difluoroallylation of aldehydes mediated by indium powder has been carried out using 2-bromomethyl-1,1-difluorodec-1-ene leading to 2,2-difluoro-3-methylenealkanols in useful yields. The reaction has been applied to a range of aldehydes including both aromatic and aliphatic aldehydes.

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