An alternative synthetic strategy for (3R),(5R)-5-hydroxy-de-O-methyllasiodiplodin and its epimer
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Add time:08/31/2019 Source:sciencedirect.com
A concise total synthesis of (3R),(5R)-5-hydroxy-de-O-methyllasiodiplodin and its epimer have been synthesized from commercially available (R)-propylene oxide and Orsellinic acid as starting materials. The key steps involved in the synthesis are Wittig reaction, epoxide ring opening with 1,3-dithiane intermediate and Yamaguchi macrolactonization.
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