Preliminary communicationNiobium metallaboranes: A novel metallaborane analogue of Pentaborane (cas 19624-22-7)(11)

Add time:09/05/2019    Source:sciencedirect.com

Treatment of [Nb(η-C5H5)2H3] with pentaborane(9) gives the novel arachno-metallaboranes [Nb(η-C5H5)2B4H9] (1) and [Nb(η-C5H5)2B3H8] (2). Compound 1 is the first reported base subrogated analogue of the neutral arachno-pentaborane(11) and has an apex to niobium hydrogen bridge. Compound 2, for which the X-ray crystal structure has been determined, is an analogue of the neutral arachno-tetraborane(10).

We also recommend Trading Suppliers and Manufacturers of Pentaborane (cas 19624-22-7). Pls Click Website Link as below: cas 19624-22-7 suppliers

Prev:The structures of bromoPentaborane (cas 19624-22-7) and of ethyl Pentaborane (cas 19624-22-7)
Next:Diruthenium analogues of Hexaborane(12) and Pentaborane (cas 19624-22-7)(9): Synthesis and structural characterization of [(1,2-Cp*Ru)2B2H6S2] and [(2,3-Cp*Ru)2B3H6(μ-η1-EPh)], (E = S, Se and Te) (Cp* = η5-C5Me5))