Preparation and characterization of functionalized poly(vinyl chloride) membranes for selective separation of perchlorate from water

Add time:09/04/2019    Source:sciencedirect.com

Perchlorate permselective membranes were synthesized and characterized in this study. The membrane with a thickness of ~300 μm was prepared with polyvinyl chloride (PVC) and quaternary ammonium salts in solvent under room temperature. Among the 12 different quaternary ammonium salts, methyltributylammonium chloride (MTBA) showed superior perchlorate permselectivity due to in part to the favorable steric effect of the alkyl chain length. In addition, results from contact angle measurements indicated that modification with quaternary ammonium salts rendered the membranes hydrophobic. Results from Fourier transform infrared (FTIR) spectrum analysis showed that the functional groups responsible for ion exchange were incorporated in the membrane matrix successfully. The surface roughness, averaged pore radius and ion exchange capacity of the MTBA membrane were 3.23±2.58 (nm), 83.6 (Å) and 0.12 (meq/g), respectively. The rate constants of anions transport across the membranes were calculated. In the presence of an electric field, about 60% of perchlorate was separated from the solution while only less than 9% of other anions, specifically, nitrate, sulfate and bicarbonate passed through the membrane under otherwise identical operation conditions simultaneously.

We also recommend Trading Suppliers and Manufacturers of TRIMETHYLAMMONIUM PERCHLORATE (cas 15576-35-9). Pls Click Website Link as below: cas 15576-35-9 suppliers

Prev:Perchlorate in seawater: Bioconcentration of iodide and perchlorate by various seaweed species
Next:Water treatment technologies for perchlorate: A review)