Catalytic decomposition of alkyl chloroformates by hexabutylguanidinium chloride
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Add time:08/30/2019 Source:sciencedirect.com
Hexabutylguanidinium chloride (0.5 molar %) efficiently decomposes alkyl chloroformates into chlorides, with low alkenes formation, via a SN2 mechanism as demonstrated from substituents effects and asymmetric chloride synthesis.
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