2-Fluoro-3-phenyl-allyltrimethylsilane: A new fluorinated reagent for Hosomi–Sakurai reaction

Add time:07/14/2019    Source:sciencedirect.com

2-Fluoro-3-phenyl-allyltrimethylsilane, prepared from β-fluorinated allylic acetate via a π-allylpalladium intermediate, reacted with various aldehydes and acetals in the presence of TiCl4 to afford the corresponding homoallyl alcohols and homoallyl ethers, respectively, in good to moderate yields.

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