Synthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid

Add time:09/03/2019    Source:sciencedirect.com

The new metal-organic framework materials based on boric acid reported herein. Sodium and boron containing metal-organic frameworks were synthesized by one-pot self-assembly reaction in the presence of trimesic acid and terephthalic acid in water/ethanol solution. Boric acid is a relatively cheap boron source and boric acid mediated metal-organic framework prepared mild conditions compared to the other boron source based metal-organic framework. The synthesized compounds were characterized by FT-IR, p-XRD, TGA/DTA, elemental analysis, 13C-MAS NMR, 11B-NMR and single crystal measurements. The molecular formulas of compounds were estimated as C18H33B2Na5O28 and C8H24B2Na2O17 according to the structural analysis. The obtained complexes were thermally stable. Surface properties of inorganic polymer complexes were investigated by BET analyses and hydrogen storage properties of compound were also calculated.

We also recommend Trading Suppliers and Manufacturers of Boric acid, sodium salt (cas 1333-73-9). Pls Click Website Link as below: cas 1333-73-9 suppliers

Prev:Study of structural, surface and hydrogen storage properties of boric acid mediated metal (sodium)-organic frameworks
Next:Molten salt synthesis of highly ordered and nanostructured hexagonal boron nitride)