Enantioselective syntheses of (−)-7-oxo-kolavenic acid and (−)-methyl solidagonate from (−)-verbenone

Add time:07/15/2019    Source:sciencedirect.com

The first enantioselective synthesis of the title neo-trans-clerodanes 3 and 4b from (−)-verbenone 5 has been accomplished using the ene reaction and stereoselective conjugate addition reaction to the enone 13 as the key step.

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