Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones
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Add time:08/30/2019 Source:sciencedirect.com
Prolonged treatment of menth-4-en-3-yl sulfides with H2O2 in acidic medium leads to saturated menthan-3-yl sulfones, the same products having been obtained from menth-4-en-3-yl sulfoxides in acidic medium in the absence of H2O2. The mechanism was evaluated by quantum chemical calculations.
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