Consecutive SRN1 and ERC1 reactions in 5-nitroisoquinolines

Add time:08/31/2019    Source:sciencedirect.com

The reaction of 1-(dichloromethyl)-5-nitroisoquinoline with 2-nitropropane anion which gives 1-isopropylidenemethyl-5-nitroisoquinoline as major product is shown to proceed by the consecutive SRN1 and ERC1 mechanisms. These mechanisms are confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and TEMPO.

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