RESEARCH PAPERThe catalytic role of aluminium trichloride (cas 15611-80-0) in the polymerization and carbonization of coal tar
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Add time:08/31/2019 Source:sciencedirect.com
The polymerization and carbonization of coal tar was carried out at different temperatures from 633 to 1873 K using aluminium trichloride (cas 15611-80-0) as catalyst. The polymerization degree, microstructures and optical texture of samples were analyzed by thermogravimetry, X-ray diffraction, Raman spectroscopy and polarized light microscopy. Results indicated that aluminium trichloride accelerated dehydrogenation during the polymerization of coal tar, and increased the toluene-insoluble fraction and carbonization yield. The presence of aluminium trichloride in the polymerized coal tar affected the microstructure of the coke by the formation of a quasi-isotropic structure.
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