Mechanistic studies on the asymmetric addition of HCN to aldehydes catalysed by cyclo[(S)-His-(S)-Phe]
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Add time:09/24/2019 Source:sciencedirect.com
The nature of the interaction between HCN and cyclo[(S)-His-(S)-Phe] during the asymmetric hydrocyanation of benzaldehyde is investigated by variable pH nmr spectroscopy. The structure of the protonated form of cyclo[(S)-His-(S)-Phe] is determined by variable temperature NMR and molecular mechanics calculations.
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