ReviewEmerging Strategies for C–H Silylation

Add time:09/04/2019    Source:sciencedirect.com

Silicon-containing molecules are of great academic and industrial interest with widespread applications in several research areas such as materials science, medicinal chemistry, and complex-molecule synthesis. C–Si bond formation by direct C–H functionalization is a modern synthetic approach toward highly valuable compounds that offers a superior step and atom economy in contrast to conventional procedures involving at least one prefunctionalized reaction partner. In this review, we summarize the different strategies for C–H silylation. Organized by their reaction mechanism, a representative selection of recent methodologies is introduced and compared with regard to their substrate scope, functional-group tolerance, and regioselectivity.

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