The formation of 3-methyl-1a,7b-dihydro-1H-cycloprop[c]isoquinoline from trans-N-[2-(2-acetylphenyl)cyclopropyl]-2-(trimethylsilyl)ethylcarbamate

Add time:07/15/2019    Source:sciencedirect.com

3-Methyl-1a,7b-dihydro-1H-cycloprop[c]isoquinoline is formed from trans-2-(2-acetylphenyl)cyclopropylamine generated in situ. The mechanism for this reaction appears to involve the formation of a cis-arylcyclopropylamine via a homoconjugated intermediate.

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