Ruthenium and OSMIUM CARBONYL (cas 15696-40-9) nitrosyl complexes: Matrix infrared spectra and density functional calculations for M(CO)2(NO)2 and M(CO)(NO) (M = Ru, Os)
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Add time:09/24/2019 Source:sciencedirect.com
Laser-ablated ruthenium or osmium atom reactions with CO and NO mixtures in solid argon produce unsaturated metal carbonyl nitrosyls including M(CO)(NO) and 18-electron configuration M(CO)2(NO)2 molecules (M = Ru, Os). The observed absorption bands of reaction products are identified by isotopic substitution, isotopic ratios and isotopic distributions (13CO, 15NO, and mixtures). DFT (B3LYP and BP86) vibrational fundamental calculations reproduce observed frequencies and isotopic shifts very well. The bonding and reaction mechanism are discussed.
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