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  • Removal of organic pollutants from 2,2′,5,5′-tetrachlorobenzidine (TCB) industrial wastewater by micro-electrochemical oxidation and air-stripping

  • Add time:09/04/2019    Source:sciencedirect.com

    A feasible method for treatment of the wastewater from the two-staged neutralization in 2,2′,5,5′-tetrachlorobenzidine (TCB) manufacturing processes, a refractory dye intermediate effluents, based on combined micro-electrochemical oxidation or iron-chipping filtration (ICF) and air-stripping reactor (ASR), was developed. On conditions of HRT 1 h, pH 3.0 in ICF and HRT 38 h, gas–liquid ratio 15, pH 6.0–8.65, temperature 26 °C in ASR, the overall COD, color, TCB and NH4+-N removal were 96.8%, 91%, 87.61% and 62%, respectively, during the treatment of TCB wastewater from the two-staged neutralization dissolved by methanol. The averaged 18.3%, 81.7% of the total degraded COD, 35.2%, 64.8% of TCB were carried out in ICF and ASR, respectively. NH4+-N removal was finished mainly in ASR. The experimental results indicated that the combined micro-electrochemical oxidation and air-stripping process performed good treatment of COD, color, TCB and NH4+-N removal in TCB wastewater from the two-staged neutralization dissolved by ethanol or acetone, came up the discharge standard in China. But the TCB wastewater from the two-staged neutralization dissolved by methanol should be deeply treated before discharged.

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