Chapter 8 - Polymerization of Allyl Esters

Add time:09/06/2019    Source:sciencedirect.com

Publisher SummaryThe 2-propene group is commonly referred to as the “allyl group.” Many natural and artificial flavoring agents contain allyl derivatives. Allyl esters are found in many perfumes. Since allyl compounds are capable of free-radical polymerization, they are used in a number of copolymer systems. Only four allyl esters are of significant industrial importance as monomers for the production of homopolymers. These prepolymers may be molded and subsequently cross-linked to give rigid plastic objects. The free-radical polymerization process with allyl esters resembles that of vinyl and acrylic esters in that there are similar initiation, propagation, and termination steps. Of particular importance in the case of allyl compounds is the chain-transfer process. It is this chain-transfer reaction, which constitutes the predominant characteristic differences between allylic and vinyl polymerization reactions.

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