Regular papersA useful method in organotin chemistry: diimine hydrogenation of 1,2-bis(trimethylstannyl)-1-alkenes, 1-trimethylsilyl-2-trimethylstannyl-1-alkenes and some distannacyclopentenes
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Add time:09/09/2019 Source:sciencedirect.com
The title compounds can be readily hydrogenated by diimine produced in situ from commercial 80% hydrazine hydrate, 30% hydrogen peroxide and a 1% copper sulphate solution. Replacement of the methyl groups on tin by butyl groups causes the consumption of the alkene to fall dramatically under standard reaction conditions.
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