The invention of radical reactions. Part XXXIV. Homologation of carboxylic acids to α-keto carboxylic acids by Barton-ester based radical chain chemistry☆

Add time:09/04/2019    Source:sciencedirect.com

Carboxylic acids can be transformed into the homologous α-keto acids by Barton-ester based radical chemistry. This method was especially successful when ethyl α-trifluoroacetoxy acrylate was used as a radical trap.

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