Photochemical oxidative addition of Hydrazinium (cas 18500-32-8) cations to tetracyanoplatinate(II) induced by OSCT excitation
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Add time:09/09/2019 Source:sciencedirect.com
The Hydrazinium (cas 18500-32-8) cations N2H62+/N2H5+ form ion pairs with [Pt(CN)4]2−. Outer-sphere charge transfer excitation (PtII → N2H62+/N2H5+) induces an oxidative addition: N2H62+/N2H5+Pt(CN)42- → [PtIV(CN)4(NH3)2] and [Pt(CN)4(NH3)(NH2)], respectively.
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