Methoxide-induced rearrangement of some N-t-butyl α-chlorophosphonamidates evidence for azaphosphiridine oxide intermediates

Add time:09/04/2019    Source:sciencedirect.com

N-t-Butyl α-chlorophosphonamidates (4) undergo methoxide-induced rearrangement to give products (6 and 7) in which either the P-N or P-C bond has been broken. This implies the intermediacy of a cyclic azaphosphiridine oxide 5.

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