Stereochemistry of the enolate from methyl phenylacetate
-
Add time:09/08/2019 Source:sciencedirect.com
Deprotonation of methyl phenylacetate with lithium diisopropylamide in tetrahydrofuran followed by trapping with trimethylsilyl chloride afforded an 81:19 mixture of E- and Z-silyl ketene acetals in agreement with a prediction by the calculation by Dauben. The E-silyl ketene acetal was readily isomerized to Z-isomer in the presence of LiCl and HMPA in THF.
We also recommend Trading Suppliers and Manufacturers of BUTYL PHENYLACETATE (cas 122-43-0). Pls Click Website Link as below: cas 122-43-0 suppliers
Prev:A phenylacetate derivative, SCK6, inhibits cell proliferation via G1 cell cycle arrest and apoptosis
Next:N-Hydroxysuccinimidyl phenylacetate as a novel derivatizing reagent for aliphatic amines in gas chromatography) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- N-Hydroxysuccinimidyl phenylacetate as a novel derivatizing reagent for aliphatic amines in gas chromatography09/09/2019
- A phenylacetate derivative, SCK6, inhibits cell proliferation via G1 cell cycle arrest and apoptosis09/07/2019
- Overriding effect of temperature over reagent and substrate size for boron-mediated aldol reaction of methyl phenylacetate09/06/2019
- The effect of substituents and operating conditions on the electrochemical fluorination of alkyl phenylacetates in Et3N·4HF medium09/05/2019
-
Health and Chemical more >
-
Related Products
- Butyl (2S)-2-hydroxypropanoate
- Butyl (3,4-dichlorophenyl)methyl 3-pyridinylcarbonimidodithioate
- Butyl (R)-( )-2-(4-Hydroxyphenoxy)-propanoate
- Butyl 10-undecylenate
- Butyl 2,2-difluorocyclopropanecarboxylate
- Butyl 2,3-Epoxypropyl Fumarate
- Butyl 2,4-dichlorophenoxyacetate
- Butyl 2-chloroacetate
- Butyl 2-methylbutyrate
- Butyl 3,4,5-trihydroxybenzoate