First allylboration of organic compounds with the NN double bond. Synthesis of N-allylpyrazolidines and allyl-1,2-Diphenylhydrazine (cas 122-66-7)
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Add time:09/05/2019 Source:sciencedirect.com
Triallylborane adds to the NN double bond of pyrazolines 1 and 2 at 0 °C giving after deboronation the corresponding N-allylpyrazolidines 4 and 5. Further transformations of allylpyrazolidine 4 including the cyclopropane ring opening were studied. Allylboration of azobenzene with triallylborane gives rise to 1-allyl-1,2-diphenylhydrazine.
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