Action of ultrasound on deoxygenated aqueous solutions of d-glucose

Add time:09/05/2019    Source:sciencedirect.com

The action of ultrasound on deoxygenated aqueous solutions of d-glucose yielded d-gluconic acid, d-arabino-hexos-2-ulose, d-ribo-hexos-3-ulose, d-xylo-hexos-4- and -5-ulose, d-gluco-hexodialdose, 2-deoxy-d-arabino-hexonic acid, 5-deoxy-d-xylo-hexonic acid, 6-deoxy-l-threo-hexos-4,5-diulose, and 6-deoxy-d-threo-hexos-2,5-diulose. There was little cleavage of the carbon skeleton. The ratio of the deoxy compounds to the sum of the hexosuloses and the hexodialdose was smaller on sonolysis than on γ-irradiation.

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