Chapter 2 - The Organometallic Chemistry of Group 10 Poly(pyrazolyl)borate Complexes

Add time:09/08/2019    Source:sciencedirect.com

Publisher SummaryPoly (pyrazolyl)borate complexes of the group-10 triad are noticeably less numerous than many transition metals. However, the study of these materials has typically proven more systematic than for many others, dominated by investigation of reactivity traits with limited incidence of purely derivative examples. This chapter is concerned only with those materials that conform to the generally accepted definition of ‘‘organometallic,’’ and those that, while not strictly organometallic, are or have the potential to be of interest and utility to the organometallic chemist. Thus, the inclusion of all complexes featuring an M-C linkage– along with related metal hydrides, phosphanes, and nitrosyls– is implicit., Classical coordination compounds are included only where these possess substantiated or perceived utility to the field (e.g., synthetic precursors, catalysts) or serve to illustrate novel structural facets of far-reaching significance. Similar discretion is applied to the inclusion of more exotic materials that currently linger at the periphery of organometallic chemistry.

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