Near-infrared luminescent materials: From β-diketonate ytterbium (cas 15751-45-8) complexes to β[email protected] thin film

Add time:09/24/2019    Source:sciencedirect.com

In view of the potential application of NIR luminescence in biology, a series of four new 3,5-Heptanedione (β-diketonate) ytterbium (cas 15751-45-8) complexes, e.g. [Yb(L)3(H2O)2] (1), [Yb(L)3(2,2′-bpy)] (2), [Yb(L)3(dpq)] (3) and [Yb(L)3(dppz)] (4) have been designed and isolated. Crystal structures analysis show that all complexes 1–4 exhibit the similar mononuclear structure, in which the central Yb3+ ion is eight-coordinated forming the square-anti-prismatic geometry. NIR luminescence of all complexes 1–4 shows strong characteristic emission of Yb3+ ions. To improve the mechanical and thermal stability, complex 1 was further doped into poly-(methyl methacrylate) (PMMA) for preparing a thin film (1@PMMA). Their thermal stability and NIR luminescence were essentially enhanced in contrast to that for complex 1. This NIR luminescent thin film may be of potential applications in biological dictation and luminescent probe.

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