MnIII-catalyzed phosphorylation of vinyl azides: The synthesis of β-keto phosphine oxides
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Add time:09/05/2019 Source:sciencedirect.com
MnIII-catalyzed functionalization of vinyl azides via phosphorylation was developed to synthesize various β-keto phosphine oxides in high yields. The transformation is operated in mild conditions and tolerant of a range of functional groups. Control reaction indicates that the reaction mechanism might proceed via the generation of a phosphonated iminyl radical intermediate.
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