Synthesis of 9,12-epoxyoctadeca-9,11-dienoic acid
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Add time:09/24/2019 Source:sciencedirect.com
The oxidation of 12-oxo-(Z)-9-octadecenoic acid with potassium permanganate in an alkaline medium is described, erythro-9,10-Dihydroxy-12-oxooctadecanoic acid and 9,12-epoxyoctadeca-9,11-dienoic acid are obtained as minor and major products, respectively. The furanoid structure of the latter acid is confirmed by spectroscopic techniques and by the preparation of derivatives.
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