Complexes of formamidines and ethyl formimidate
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Add time:09/06/2019 Source:sciencedirect.com
Formamidines and formimidates (L = (p-MeC6H4 NH)(p-MeC6H4N=)CH; L′ = (p-MeC6H4N=) (EtO)CH are shown to yield metal complexes, not obtained directly before. The following complexes were characterized through spectral and magnetic data: L2Ag+, L2AgNO3, L2ZnBr2, L2CdBr2, L3Cd2Br4, LHgCl2, L2CoCl2, [LH]2[CoCl4], cis-(CO)2RhClL as well as L′2Ag+ and cis-(CO)2RhClL′. I.r. and n.m.r. spectra allow to distinguish these complexes from the derivatives of the isomer carbene ligands, (RNH)2C: and (RNH)(R′O)C:.
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