Some cobalt complexes with a multidentate substituted phosphine

Add time:09/08/2019    Source:sciencedirect.com

The quadridentate ligand tris-(o-diphenylphosphinophenyl) phosphine (QP) forms complexes with cobalt(II) of the type [CoX(QP)]Y which have S = 12 and which have been assigned a distorted trigonal bipyramidal structure. Trigonal-bipyramidal, diamagnetic, complexes of cobalt(I) of the type [Co(CO)(L)]+ (L = QP and QAS) and octahedral, diamagnetic complexes of cobalt (III) of the type [CoX2(QP)]+ are also described

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