Sol–gel encapsulated cobalt(III) acetylacetonate for air oxidation of penicillin derivatives

Add time:09/09/2019    Source:sciencedirect.com

The sulfoxides of penicillin derivatives are important pharmaceutical intermediates and can be prepared by air oxidation of corresponding sulfides catalyzed by COBALT(III) ACETYLACETONATE (cas 13681-88-4) (Co(acac)3). However, when using the homogeneous catalyst, it is very difficult to separate the catalyst from product, which makes it impossible to reuse the catalyst directly. While the heterogeneous Co(acac)3 encapsulated by sol–gel method can solve the problem. They have high selectivity and activity. They are leach proof and can be recycled in numerous runs. The sol–gel precursor can be tetraethoxysilane (TEOS) or tetrabutyl titanate (TBOTi) or triisopropyl aluminate (TIOAl). FT-IR and N2 adsorption was employed to characterize the sol–gel catalyst. HPLC was used to analyze the conversion of penicillin derivatives.

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