Carbonyl complexes of rhodium with Lewis bases: Molecular structure of cis-chlorodicarbonyl(TRICYCLOHEXYLPHOSPHINE OXIDE (cas 13689-19-5))rhodium(I)
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Add time:09/27/2019 Source:sciencedirect.com
The reaction of [RhCl(CO)2]2 with tricyclohexylphosphine oxide (Cy3PO) (Rh/Cy3PO molar ratio 1) gives the dicarbonyl derivative, cis-[RhCl(CO)2(Cy3PO)], which is stable toward loss of carbon monoxide and subsequent dimerization. An X-ray structure determination shows that the rhodium is in a square-planar cis-dicarbonyl configuration.
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