Original articleDecarboxylative bromination of α,β-unsaturated carboxylic acids via an anodic oxidation
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Add time:09/08/2019 Source:sciencedirect.com
A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation. In this method, ammonium bromide was employed as a bromine source and the reaction features transition-metal-free, short time, and no additional supporting electrolyte.
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- Intramolecular carboxylate capture of an intermediate in aromatic electrophilic substitution. The 8,9,10,11-tetrahydro-7.11-methano-7H-cycloocta[de]naphthalene-9-endo-carboxylic acid system09/09/2019
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