Equilibrium and kinetic studies on acid dye ACID RED 88 (cas 1658-56-6) adsorption by magnetic ZnFe2O4 spinel ferrite nanoparticles
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Add time:09/24/2019 Source:sciencedirect.com
A magnetic ZnFe2O4 (MNZnFe) was synthesized by microwave assisted hydrothermal method and was used as an adsorbent for the removal of acid dye ACID RED 88 (cas 1658-56-6) (AR88) from aqueous solution. The effects of various parameters such as initial AR88 concentration (10–56 mg L−1), pH solution (3.2–10.7), and temperature (20–60 °C) were investigated. Prepared magnetic ZnFe2O4 was characterized by XRD, SEM, HRTEM, ICP-AES, BET, FTIR, and measurements of the magnetic susceptibility. The experimental data were analyzed by the Langmuir and Freundlich models of adsorption. Equilibrium data fitted well with the Langmuir model. Pseudo-first-order and pseudo-second-order kinetic models and intraparticle diffusion model were used to examine the adsorption kinetic data. The adsorption kinetics was found to follow the pseudo-second-order kinetic model. Thermodynamics parameters, ΔG°, ΔH° and ΔS°, indicate that the adsorption of AR88 onto MNZnFe was spontaneous and exothermic in nature.
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