Poly[(2-ethylhexyl acrylate)-ran-(tert-Butyl acrylate (cas 1663-39-4))]-block-poly(2-cinnamoyloxyethyl acrylate) synthesis and properties

Add time:09/26/2019    Source:sciencedirect.com

Poly[(2-ethylhexyl acrylate)-ran-(tert-butyl acrylate)]-block-poly(2-cinnamoyloxyethyl acrylate) or P(EXA-r-tBA)-PCEA was synthesized by atom transfer radical polymerization. Reactivity ratios of EXA and tBA for copolymerization were determined. The specific refractive index increments of six diblocks were measured as a function of their composition. The diblocks were thermally stable and formed micelles in an automobile engine oil. Such micelles may be useful as an anti-friction additive in lubricating oils.

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