Regular ArticleExcess enthalpies of (benzene  +  benzene-d6), (cyclohexane  +  cyclohexane-d12) and (dichloromethane +  DICHLOROMETHANE-D2 (cas 1665-00-5)) atT =  298.15 K

Add time:09/07/2019    Source:sciencedirect.com

Precise and accurate values of the excess enthalpies of{xC6H6 +  (1  − x)C6D6} ,{xC6H12 +  (1  − x)C6D12} and{xCH2Cl2 +  (1  − x)CD2Cl2} have been determined over the whole composition range at T =  298.15 K. Although all the excess enthalpies are small, those of{xC6H6 +  (1  − x)C6D6} and{xC6H12 +  (1  − x)C6D12} are endothermic and those of{xCH2Cl2 +  (1  − x)CD2Cl2} are exothermic. A linear correlation is found between the excess enthalpies at x =  0.5 and the reciprocal of the number of deuterium atoms bound to the carbon atoms of a deuterated compound.

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