Unexpected behavior of the methoxymethoxy group in the metalation/formylation reactions of 3-methoxymethoxyanisole

Add time:09/07/2019    Source:sciencedirect.com

The formation of tetrasubstituted benzenes and doubly lithiated intermediates in metalation/formylation reactions of 3-methoxymethoxyanisole has been observed with the methoxymethoxy group acting as a leaving group in some cases.

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