Reduction of CO to methanol by everitt's salt using pentacyanoferrate(II) or pentachlorochromate(III) and methanol as homogeneous catalysts

Add time:09/07/2019    Source:sciencedirect.com

The reduction of CO to methanol by Everitt's salt has been studied at room temperature and atmospheric pressure. The CO reduction is caused by the oxidation reaction of Everitt's salt to Prussian blue. However, this redox reaction can only be activated by the coexistence of a metal complex and methanol used as homogeneous catalysts. Pentacyanoferrate(II), amminepentacyanoferrate(II) and pentachlorochromate(III) operated as effective catalysts, but pentacyanonitrosylferrate(III) and hexacyanoferrate(II) did not.

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