Micellar effects upon the alkaline hydrolysis of 2-(3-nitrophenoxy)quinoxaline. Effects of cationic head groups
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Add time:09/08/2019 Source:sciencedirect.com
The rate of alkaline hydrolysis of the novel compound 2-(3-nitrophenoxy)quinoxaline 1 increases with increasing head group size in a series of cationic micellized surfactants (C16H33NR3Cl and C16H33NR3OH: R = Me, Et, n-Pr and n-Bu). The reactivity increase with increasing head group size is related to the disruption of the hydration of hydroxide ion.
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